Therefore, slight heating breaks the bond existing between the oxygen and metal atom. Thermal stability of alkaline earth metal carbonates decreases in the order (A) BaCO3 > SrCO3 > CaCO3 > MgCO3 (B) BaCO3 > SrCO3 > MgCO3 > CaCO3 (C) Ca share | improve this question | follow | edited Feb 24 '18 at 4:52. The carbonates of alkaline earth metals and Lithium carbonate decompose on heating to form oxides with the evolution of CO2. What is order of thermal stability of carbonates of alkaline earth metals? Add your answer and earn points. * The carbonates of alkaline earth metals can be regarded as salt weak carbonic acid and metal hydroxide, * Bicarbonates of these metals do not exist in solid state. So thermal stability increases. Log in. Ask for details ; Follow Report by Dishagrover3703 3 weeks ago Log in to add a comment What do you need to know? 2M(NO 3) 2 → 2 MO + 4 NO 2 + O 2 (M = Be, Mg, Ca, Sr or Ba) The nitrates of Na, K, Rb and Cs decompose to form metal nitrites and O 2. #ChemistrySuperKing#CollegeSeries#ETEA #MDCAT#NEET#IIT#JEE#PCS#Tricks#Concepts #Thermal_Stability#Carbonates#Nitrates#Alkaline#Earth#Metals. I used Fajan's rule to check for ionic character but somehow this is only applicable for carbonates. I cannot wrap my head around this. 1 See answer atul77718 is waiting for your help. Solubility and thermal stability of carbonates of alkaline earth metals increases on moving down the group due increase in the size of metal ions. Those metal carbonates which do decompose leave a residue of the metal oxide and evolve carbon dioxide in the process, eg: ZnCO 3 (s) → ZnO(s) + CO 2 (g) At an elementary level, the relative thermal stability of the carbonates of the metals cannot easily be explained in terms of simple ideas of bonding in these compounds. Biology. Alkaline earth metals have low electrode potentials, and so are obtained by the electrolysis of the fused chlorides. For example, 200 mg samples of pure graphite powder and intimate mix- tures of graphite powder with 0.5 and 5.0 wt % finely ground BaC03 were heated in the thermobalance in a flowing … RESULTS Catalysis by alkaline earth carbonates The effects of small amounts of the carbonates of the Group IIA metals on the reactivity of graphite towards COz were studied as a function of temperature. because down the group polarizing power of cation decreases. Similar to lithium nitrate, alkaline earth metal nitrates also decompose to give oxides. Stability of carbonates increases down group I (alkali) and group II (alkaline earth) metals. Thermal stability. The carbonates of alkaline earth metals also decompose on heating to form oxide and carbon dioxide. BeCO 3 is unstable and kept only in the atmosphere of CO 2. NCERT P Bahadur IIT-JEE Previous Year Narendra Awasthi MS Chauhan. Thermal stability of Alkaline earth metals carbonates increases down the group. The sulphates of alkaline earth metals are stable to heat . OCCURRENCE. The carbonates of alkaline earth metals are sparingly soluble in water. The stability of alkaline earth metals increases down the group and they decompose on red heating. All alkaline earth metal nitrates decompose to form metal oxide, NO 2 and O 2. Physics . 1. Maths. This video is unavailable. Group-2 (alkaline earth metals) carbonates MCO 3: MgCO 3, CaCO 3, BaCO 3 etc., bicarbonates M(HCO 3) 2: Mg(HCO 3) 2, Ca(HCO 3) 2 etc., p-block elements carbonates _ Tl 2 CO 3 and PbCO 3: Transition elements carbonates _ ZnCO 3, CuCO 3, Ag 2 CO 3, FeCO 3 etc.,. Ask your question. Beryllium carbonate is unstable and should be kept in the atmosphere of CO 2. Ask your question. Carbonates of alkaline earth metals are relatively less stable towards heat and decompose to CO2; MCO 3 → MO + CO 2 ( M = Be, Mg , Ca , Sr, Ba) However , their stability increases as we move down the group . The carbonates become less soluble down the group. Nitrates of alkali metals, except LiNO 3, decompose on strong heating to form nitrites. Also, for the same period the group 1 carbonate is relatively more stable. From Li to Cs, due to larger ion size, hydration enthalpy decreases. The bicarbonates of all the alkali metals are known. Thermal stability of alkali metal carbonate---- alkali metals carbonates are stable and do not decompose even at high temperature. NCERT NCERT Exemplar NCERT Fingertips Errorless Vol-1 Errorless Vol-2. All these carbonates decompose on heating to give CO 2 and metal oxide. The alkaline earth metals are said to have a higher ability to distort the oxygen cloud compared to the alkaline metals. NCERT DC Pandey Sunil Batra HC Verma Pradeep Errorless. LiNO 3 , on decomposition, gives oxide. Gaurang Tandon. The temperature at which these carbonates decompose are : BeCO 3: MgCO 3: CaCO 3: SrCO 3: BaCO 3 < 373 K: 813 K: 1173 K: 1563 K: 1636 K: Thermal stability increases. Solubility. The thermal stability of alkaline earth metal carbonates–MgCO3, CaCO3, SrCO3 and BaCO3, follows the order asked Apr 30, 2019 in Chemistry by RenuK ( 68.1k points) kvpy I used Fajan 's rule to check for ionic character but somehow this is only applicable for carbonates substance likely. 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